
construction maximizer contains one at any
n
, for the structural reason given by Proposition 12.1:
the sector Ω
N,0
consists of all-lift histories and a lift produces only tetrahedra. Such all-tetrahedral
complexes are moreover geometrically strained, since a pure tetrahedral fan around an edge cannot
close and leaves the residual deficit
δ
5
of Eq.
(6)
. Since the spatial flatness of Lemma 9.1 rests
on the tetrahedral–octahedral honeycomb, in which two tetrahedra and two octahedra meet at
every edge, the octahedral cell is exactly the structure the geometric argument requires and the
construction-bond sector cannot supply.
7.2 Agreement with the sphere-packing literature
The crossover is not an artifact of the stitch–lift move set. The same transition was found by
Arkus, Manoharan and Brenner [
6
] for clusters of hard spheres with short-range attraction, by
graph-theoretic enumeration combined with geometry rather than by lattice growth. They report
that ground-state degeneracy grows exponentially for
n ≤
9 but decreases for
n >
9 through the
appearance of packings with more than 3
n −
6 contacts, and identify octahedra and half-octahedra
as the structures responsible. Their maximal contact numbers are 3
n −
5, 3
n −
4 and 3
n −
3 at
n
= 10
,
11
,
12, which are the values in Table 2. The degeneracy collapse is likewise reproduced, from
31 contact maximizers at
n
= 9 to a unique one from
n
= 11 onward. The contact-number problem
for small n is reviewed by Bezdek and Khan [7].
That the stitch–lift moves attain the known optima is itself informative: the move set of Section 2
is not too impoverished to reach the contact-maximizing configurations, so the separation in Table 2
reflects the choice of Hamiltonian and not a limitation of the dynamics.
7.3 What this settles, and what it does not
Assumption 10.1 asserts that maximally bonded embedded states approach Barlow close packing.
The enumeration supports it in the range computed: Arkus et al. find the maximal-contact clusters
at
n
= 10
,
11
,
12 to be subsets of close-packed crystals, and the present enumeration reaches those
same configurations. The assumption is therefore no longer bare; it is verified at small
n
and open
in the thermodynamic limit.
One qualification is essential and works in the paper’s favor. The small-
n
maximal-contact
clusters are reported as subsets of hexagonal close packing. At twelve spheres a cluster is far too
small to distinguish FCC from HCP: both are Barlow packings, and small fragments are common to
the two. Contact maximization therefore delivers close packing but does not by itself select FCC.
This is precisely the tie that the chirality-transporting Lift of Section 10 breaks. Assumptions 10.1
and 10.4 are consequently not two hedges on the same step but a decomposition of the geometric
problem into distinct parts: the contact Hamiltonian selects Barlow packing, and the transported
frontier orientation selects the ABC branch within it.
What remains open is the thermodynamic statement. Twelve nodes cannot exhibit an FCC bulk
node, which requires twelve neighbors together with populated second and third shells. Establishing
that the reachable maximizers of
B
cont
approach Barlow packings as
n → ∞
, and reformulating the
detailed-balance construction of Section 3 with
B
cont
in place of
B
hist
, are the two remaining steps
between the stochastic mechanism proved here and the geometric conclusion. Neither is addressed
in this paper.
8